Interesting conundrum. I have only used tanks that already have a pipe flange built on to them, but I think you could plastic weld or epoxy one where you need. In other words, epoxy or plastic weld a flange at the bottom, not 3/4 up, and then put your blade valve on the end of that, about an inch or two away from the tank. Then your elbow and the rest through the floor.
I think you would ruin the tank and the odor seal by putting a hole in the top and going to the trouble of trying to fish a piece down into that corner. That looks way too risky and difficult to me. Can the company you got the tank from provide a flange (piece of pipe) in the exact tank material you could just plastic weld into place?