The mercaptan used to scent propane has a long shelf life.
Even residual propane from coupling and decoupling appliances can leave some behind. The heat in the box only makes it worse.
That said my Mom had a tank vent its excess pressure once while it sat in a sunny, hot backyard.
Test the valve with a soapy water solution and look for bubbles. Pour the solution directly into the valve opening with the tank on its side. They can leak from three places. At the threads of the unit, the valve shaft, and of course the output zone.
That said, life is short. Buy a new cylinder.
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