Start with the basics...
On the 6.0, you should always be able to read the following:
-ECT vs EOT (because the ECT to EOT delta is a leading indicator of a failing oil cooler)
-Injection control pressure (ICP) and ICP duty cycle. Low ICP could be a plugged HPOP screen or bad HPOP.
-Battery voltage and FICM voltage. Low FICM voltage will wipe out the injectors. Low alternator voltage will cause low FICM voltage.
-Cylinder contribution aka balance test. This identifies any individual fuel injector issues.
The 6.0 does not need a cat except in CA because it came with one. It doesn't really make it any cleaner however, unlike a gas motor. It certainly wouldn't hurt to pull yours out to inspect it. It's pretty obvious when it's had a melt-down. If it did, you could punch out guts and put the housing back as a test. That said... something else likely caused that, if that's the case. Sticking injector could do this.
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2000 E450 dually V10 wagon
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